Zapping orange peel oil into new, pleasant aroma compounds

Limonene is regularly used in its original form, but it can also be the starting platform for other scents. But synthetic oxidation techniques that can perform this transformation have traditionally required environmentally harmful substances, such as strong chemicals and heavy metals. So, Holger Zorn and colleagues tested an environmentally benign oxidation method, mixing limonene with ethanol and applying an electrical current to the solution. The process generated an amber-colored liquid with a pleasant odor and 17 different compounds that had fruity, herbal, citrus and resinous notes. According to the researchers, this is the first time that most of these compounds have been described.

The simple, sustainable method could create valuable aroma compound mixtures for flavorings or fragrances, but the compounds must be evaluated for safety before use in commercial products, the researchers say.

The authors acknowledge funding from Landes-Offensive zur Entwicklung Wissenschaftlich-ökonomischer Exzellenz (LOEWE)-AromaPlus (State Offensive for the Development of Scientific and Economic Excellence).

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Journal Reference:

1. Florian Birk, Heike Hausmann, Marco A. Fraatz, Axel Kirste, Nicola C. Aust, Ralf Pelzer, Holger Zorn. Generation of Flavor-Active Compounds by Electrochemical Oxidation of (R)-Limonene. Journal of Agricultural and Food Chemistry, 2022; DOI: 10.1021/acs.jafc.2c01301